Conclusion
The analysis of photophysical constants allows to make the following basic conclusions:
- The radiating channel of decay of state S1* in anion is dominant, while in
the neutral form probability of a crossing of a molecule in triplet states is great, so
the intercrossing constant between the first singlet and fifth triplet states (KST
= 109 s-1) is comparable on magnitude to a constant of radiative
decay of a molecule from S1* (108 s-1).
- In the cation form at excitation of quantum of light < 250 nm singlet - triplet
conversion between S4* and T6*
states is probable.
- In tautomeric form np * state is located in the region ~ 300 nm, that by using the excimer laser with a wavelength of
excitation 308 nm results in reduction on efficiency of generation of ethanol solutions
4MU [7] because of the effective intercrossing conversion between S3* and T7* energy levels.
